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4.4 Robust radiotherapy Radiotherapy (RT) is critical for cancer therapy, and about 50% of patients will receive ionizing radiation during their treatment period ( As a paradigm, Wu and co-workers integrated Au nanoclusters (Au NCs) with histidine to accomplish GSH exhaustive-prompted RT, denoted as Au NCs@His (Figure 7A) ( via depleting GSH with the ability of forming Au-S bond (Figure 7B)